Kinetic Conversion of Carbon Dioxide in Supported Tungsten Carbide Catalysts and Oxide Catalysts for the Reverse Water Gas Shift Reaction
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Abstract
The reverse water-gas shift reaction (RWGS) had a critical stage in the conversion of abundant carbon dioxide into chemicals or hydrocarbon fuels and has attracted widespread interest as a renewable fuel assembly system in unconventional ways. Interest has been in industrial applications such as the catalytic activity, carbon dioxide conversion, kinetics, and efficacy levels of tungsten carbide-supported catalysts and carbide oxide catalysts for the production of RWGS reaction. Additionally, carbide oxides have the ability to enhance RWGS and develop high-performance catalysts in RWGS. The RWGS reaction was (CO2 + H2 ↔ CO + H2O; ΔG°=27.94kJ/mol) an exothermic reaction that exhibits equilibrium conversion with temperature.
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Salma Korbag, & Issa Korbag. (2022). Kinetic Conversion of Carbon Dioxide in Supported Tungsten Carbide Catalysts and Oxide Catalysts for the Reverse Water Gas Shift Reaction. Sindh University Research Journal - SURJ (Science Series), 54(1). https://doi.org/10.26692/surj.v54i1.4497
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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
References
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[12]. Korbag, S. M. S. O., &Korbag, I. M. S. O. (2020). Reverse water gas shift reaction over tungsten carbide prepared catalyst from waste date palm fronds at low temperatures reverse water gas shift reaction. Asian Journal of Green Chemistry, 4(1), 60-74.
[2]. Mendes, D., A. Mendes, L. M. Madeira, A. Iulianelli, J. M. Sousa and A. Basile (2010). "The water-gas shift reaction: from conventional catalytic systems to Pd-based membrane reactors—a review." Asia-Pacific Journal of Chemical Engineering5(1): 111-137.
[3]. Silva, J. (2013). Packed bed membrane reactor for the water-gas shift reaction: experimental and modeling work. (Master’s Thesis) Multiphase Reactors Group, Department of Chemical Engineering & Chemistry, Eindhoven University of Technology.
[4]. Goguet, A., Meunier, F., Breen, J. P., Burch, R., Petch, M. I., &Ghenciu, A. F. (2004). Study of the origin of the deactivation of a Pt/CeO2 catalyst during reverse water gas shift (RWGS) reaction. Journal of Catalysis, 226(2), 382-392.
[5]. Tibiletti, D., Goguet, A., Meunier, F. C., Breen, J. P., & Burch, R. (2004). On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction. Chemical communications, (14), 1636-1637.
[6]. Chen, C. S., Cheng, W. H., & Lin, S. S. (2003). Study of reverse water gas shift reaction by TPD, TPR and CO2 hydrogenation over potassium-promoted Cu/SiO2 catalyst. Applied Catalysis A: General, 238(1), 55-67.
[7]. Unde, R.B. (2012). Kinetics and Reaction Engineering Aspects of Syngas Production by the Heterogeneously Catalysed Reverse Water Gas Shift Reaction. (Doctoral Thesis), UniversitätBayreuth,FakultätfürIngenieurwissenschaften).
[8]. Bustamante, F., Enick, R., Rothenberger, K., Howard, B., Cugini, A., Ciocco, M., and Morreale, B. (2002). Kinetic study of the reverse water gas shift reaction in high-temperature, high-pressure homogeneous systems. Fuel Chemistry Division Preprints, 47(2), 663.
[9]. Bustamante, F., Enick, R. M., Killmeyer, R. P., Howard, B. H., Rothenberger, K. S., Cugini, A. V., Morreale, B. D., and Ciocco, M. V. (2005). Uncatalyzed and wall‐catalyzed forward water–gas shift reaction kinetics. AIChE journal,51(5), 1440-1454.
[10]. Yacob, A.R., Omar, S. M.S., Suleiman, K., Omar, I.M.S., Swaidand, H.M., (2014). Effect of Potassium on Date Palm Fronds in the Production of Microwave Induced Alloying. World Applied Sciences Journal, 31(4): 676-680, 2014.
[11]. Omar, S. M. S., & Omar, I. M. S. (2015). Study of Properties of Activated Carbon Produced from Agricultural Waste Date Palm Fronds. American-Eurasian Journal of Toxicological Sciences, 7(4): 247-250.
[12]. Korbag, S. M. S. O., &Korbag, I. M. S. O. (2020). Reverse water gas shift reaction over tungsten carbide prepared catalyst from waste date palm fronds at low temperatures reverse water gas shift reaction. Asian Journal of Green Chemistry, 4(1), 60-74.